Presented here are two metal-organic frameworks, namely [Zn(L)(bbp)](n) (1) and [Cu(L)(bix)(0.5)](n) (2) (H2L = 2-[(2-carboxyphenyl)disulfanyl]benzoic acid, bpp = 1,3-bis(4-pyridyl)propane, bix = 1,4-bis(imidazole-1-ylmethyl)benzene), which are synthesized under hydrothermal conditions. During this process, the 2-sulfanylbenzoic acid in situ transformed into H2L via the formation of disulfide bond. X-ray diffraction revealed that compound 1 displays a 3-fold interpenetrated 3D framework with 4-connected bcu topology, and compound 2 shows a 2D layered structure based on paddle-wheel shaped dinuclear [Cu-2(COO)(4)] subunits and represents a 4-conneceted sql topology. Luminescence test revealed that compound 1 may be served as a good blue luminescent material. Photocatalytic experiment indicated that compound 2 may be applied as a highly effective photocatalyst for the photodegradation of MB aqueous solution under UV light irradiation.
基金：
Foundation of Hebei Education Department [ZD2022084, ZD2020193]
第一作者机构：[1]Hebei Coll Ind & Technol, Univ City Country Dept Environm & Chem Engn, Shijiazhuang 0590091, Hebei, Peoples R China
通讯作者：
推荐引用方式(GB/T 7714)：
Guo L-D,Zhao X-H,Liu Y-Y,et al.In Situ Ligand Synthesis Afforded Two New Metal-Organic Compounds: Luminescent and Photocatalytic Properties[J].RUSSIAN JOURNAL OF INORGANIC CHEMISTRY.2022,67(13):2140-2147.doi:10.1134/S0036023622700097.
APA：
Guo, L-D,Zhao, X-H,Liu, Y-Y,Zuo, X-R,Yao, J....&Li, W-H.(2022).In Situ Ligand Synthesis Afforded Two New Metal-Organic Compounds: Luminescent and Photocatalytic Properties.RUSSIAN JOURNAL OF INORGANIC CHEMISTRY,67,(13)
MLA：
Guo, L-D,et al."In Situ Ligand Synthesis Afforded Two New Metal-Organic Compounds: Luminescent and Photocatalytic Properties".RUSSIAN JOURNAL OF INORGANIC CHEMISTRY 67..13(2022):2140-2147
